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One of the difficulties in preparing accurate ambient-temperature model complexes for heme proteins, particularly in the ferric state, has been the generation of mixed-ligand adducts: complexes with d...
Recently, heme protein cavity mutants have been engineered in which the proximal coordinating amino acid has been replaced by a smaller, noncoordinating residue leaving a cavity that can be filled by ...
UV-visible absorption and magnetic circular dichroism (MCD) data are reported for the cavity mutants of sperm whale H93G myoglobin and human H25A heme oxygenase in their ferric states at 4 degreesC. D...
Background: Iron fortification of rice is a promising strategy for improving iron nutrition. However, it is technically challenging because rice is consumed as intact grains, and ferric pyrophosphate ...
Ferric hydrogen sulfate was used as an environmentally friendly heterogeneous acidic catalyst for the greener, 1-pot, 3-component synthesis of 1,8-dioxo-octahydroxanthene via condensation reactions be...
Recently there has been recognition of the importance of reductive processes in the acquisition of iron by microorganisms in marine environments with Fe(III) reduction induced by either membrane-bound...
The UV-visible absorption bands of the new complex were obtained using p-amino-N, N-dimethyl aniline as an electron donor with ferric nitrate as an electron acceptor in methanol at 25°C. The values o...
Forestimationsof P-T conditionsofigneousandmetamorphicrocks,Fe incoexisting mineralsiseitherassumedtobezerooriscalculatedfromelectronmicroprobeanalyses (EMPA)baseduponstoichiometryandchargebalance.G...
An atomistic computer simulation study was undertaken to address the role of Al in the substitution of ferric iron into magnesium silicate perovskite, MgSiO 3. Calculated substi-tution and vacancy en...
Abstract: Hisingerite, first described in 1810, has been variously regarded as noncrystalline, as a septechlorite, as ferric allophane, as ferric halloysite and as poorly crystalline nontronite. Hisin...
We present a new oxybarometer for magnesiowu¨stite-bearing systems, which is easily applied using widely available techniques. A scale relating the proportion of Fe31[a5Fe31/(Fe311 Fe21)] to the posit...
Sanidine crystals precipitating from lamproitic magmascharacteristically contain ap-preciableamounts ofFeH. Sanidinegrainsfrom the LeuciteHillslamproites (Wyoming) have compositions in whichupto 70mol...
The role of adsorbed and structural Fe3+ in palygorskite and sepiolite with respect to the oxidation of hydrocortisone in aqueous suspension has been evaluated using electron spin resonance and UV-vis...
The variation with time of exchangeable surface charge of amorphous ferric hydroxide in aqueous suspension was monitored by a titration technique. After 120 days, the surface charge of suspensions wit...
Abstract: The interaction of water with synthetically prepared goethite (α-FeOOH) and amorphous hydrated ferric oxide surfaces was studied using i.r. absorption and water vapor adsorption measurements...

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