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Calculation of Electrostatic Interlayer Bonding Energy and Lattice Energy of Polar Phyllosilicates: Kaolinite and Chlorite
Chlorite Electrostatic energy Interlayer bonding Kaolinite Lattice energy
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2012/2/6
The electrostatic lattice energy of polar phyllosilicates can be calculated when a correction term Ecorr equal to −2鸬2/V is taken into account, where ?is the dipole moment of a slice d(001) and ...
Hydroxyl Orientations and Interlayer Bonding in Amesite
Amesite Fluorine Hydroxyl orientation Interlayer bonding Serpentine
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2012/2/8
The hydroxyl orientations in the 2H2 polytype of amesite, Mg2Al(SiAl)O5(OH)4, have been determine by minimizing the electrostatic potential energy as a function of OH orientation. The angles, ρ, betwe...
The Influence of Hydroxyl Orientation, Stacking Sequence, and Ionic Substitutions on the Interlayer Bonding of Micas
Hydroxyl Orientation Stacking Sequence Ionic Substitutions Micas
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2012/2/13
Hydroxyl orientation has a major influence on the strength of the ionic interlayer bonding in micas because of the strong repulsion between the hydrogen and the interlayer cation (IC). In order to det...
New Approach to the Problem of the Interlayer Bonding in Kaolinite
Interlayer Kaolinite New Approach
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2012/2/13
The possibility of recording the absorption band which is related to oscillations of free OH in a superficial plane of the octahedral sheet of kaolinite inspired the present authors to review the prob...
Interlayer Bonding in Kaolinite, Dickite and Nacrite
Interlayer Bonding Kaolinite Dickite Nacrite
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2012/2/15
A simple electrostatic model has been used to demonstrate that the inner surface hydroxyls in kaolinite, dickite and nacrite are responsible for the interlayer bonding in these minerals. The contribut...