搜索结果: 1-15 共查到“理学 relaxation”相关记录91条 . 查询时间(0.066 秒)
On the Origin of Heme Absorption Band Shifts and Associated Protein Structural Relaxation in Myoglobin Following Flash Photolysis
transhydrogenase NAD NADP Escherichia coli proton pump metal ion
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2016/5/23
The role of the protein structural change monitored by absorption band shifts following flash photolysis of CO from myoglobin is discussed in terms of structure-function relationships. Evidence is pre...
Dynamics of Protein Relaxation in Site-Specific Mutants of Human Myoglobin
Humans Cysteine Heme Alanine Myoglobin Recombinant Proteins Spectrophotometry Mutagenesis,Site-Directed Amino Acid Sequence Protein Conformation
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2016/5/23
We have recently reported spectroscopic evidence for structural relaxation of myoglobin (Mb) following photodissociation of MbCO [Lambright, D. G., Balasubramanian, S., & Boxer, S. G. (1991) Chem. Phy...
Dielectric Relaxation in a Protein Matrix
biology and medicine, basic studies chemistry proteins solvation dielectric properties time dependence relaxation fluorescence
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2016/5/23
We report measurements of time-dependent solvation in a protein medium by the fluorescence dynamic Stokes shift method. Picosecond time-correlated single photon counting fluorescence decays on the com...
Protein Relaxation Dynamics in Human Myoglobin
Protein Relaxation Dynamics Human Myoglobin
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2016/5/23
Transient absorption spectra in the Soret region have been measured following the photolysis of human MbCO in 75%(w/w) glycerol:water at 250, 270, and 290 K. The peak of the transient difference spect...
Characterization of the Overall and Internal Dynamics of Short Oligonucleotides by Depolarized Dynamic Light Scattering and NMR Relaxation Measurements
Overall and Internal Dynamics Short Oligonucleotides Depolarized Dynamic Light Scattering NMR Relaxation
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2016/5/23
The dynamics of three synthetic oligonucleotides d(CG)4, d(CG)6, and d(CGCGTTGTTCGCG) of different length and shape were studied in solution by depolarized dynamic light scattering (DDLS) and time-res...
Synthesis of a Thymidine Phosphoramidite Labelled with 13C at C6: Relaxation Studies of the Loop Region in a 13C Labelled DNA Hairpin
Thymidine Phosphoramidite Labelled 13C C6 Relaxation Studies 13C Labelled DNA Hairpin
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2016/5/20
A thymidine phosphoramidite labelled at C6 with 13C has been synthesized, and incorporated into a synthetic oligonucleotide, d(CGCGT*T*GT*T*CGCG), which adopts a hairpin conformation. NMR relaxation m...
Continuum approach to self-similarity and scaling in morphological relaxation of a crystal with a facet
Continuum approach self-similarity and scaling morphological relaxation crystal with a facet
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2015/10/16
The morphological relaxation of axisymmetric crystal surfaces with a single facet below the roughening transition temperature is studied analytically for diffusion-limited sDLd and attachment-detachme...
CONTINUUM RELAXATION OF INTERACTING STEPS ON CRYSTAL SURFACES IN 2+1 DIMENSIONS
crystal surface epitaxial growth morphological evolution Burton–Cabrera–Frank model Ehrlich–Schwoebel barrier entropic interactions elastic dipole interactions step chemical potential continuum limit surface mobility
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2015/10/16
We study the relaxation of crystal surfaces in 2+1 dimensions via the motion ofinteracting atomic steps. The goal is the rigorous derivation of the continuum limit. The starting point is a discrete sc...
Unified continuum approach to crystal surface morphological relaxation
Unified continuum approach crystal surface morphological relaxation
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2015/10/16
A continuum theory is used to predict scaling laws for the morphological relaxation of crystal surfaces in two independent space dimensions. Our goal is to unify previously disconnected experimental o...
Anisotropic diffusion in continuum relaxation of stepped crystal surfaces
Anisotropic diffusion continuum relaxation stepped crystal surfaces
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2015/10/16
We study the continuum limit in 2+1 dimensions of nanoscale anisotropic diffusion processes on crystal surfaces relaxing to become flat below roughening. Our main result is a continuum law for the sur...
ELECTROMIGRATION IN MACROSCOPIC RELAXATION OF STEPPED SURFACES
epitaxial relaxation crystal facet Burton–Cabrera–Frank model electromigration desorption surface diffusion step chemical potential macroscopic limit variational principle
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2015/10/16
We study the effect of an external electric field E on macroscopic relaxation laws for crystal surfaces in 2 + 1 dimensions. We derive a nonlinear, fourth-order partial differential equation (PDE) for...
DISCRETE AND CONTINUUM RELAXATION DYNAMICS OF FACETED CRYSTAL SURFACE IN EVAPORATION MODELS
crystal surface evaporation facet Burton–Cabrera–Frank model subgradient formalism free-boundary problem shock
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2015/10/16
We study linkages of two scales in the relaxation of an axisymmetric crystal with a facet in evaporation-condensation kinetics. The macroscale evolution is driven by the motion of concentric circular,...
Role of chemical potential in relaxation of faceted crystal structure
chemical potential relaxation faceted crystal structure
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2015/10/16
Below the roughening transition, crystal surfaces have macroscopic plateaus, facets, whose evolution is driven by the microscale dynamics of steps. A long-standing puzzle was how to reconcile discrete...
Relaxation creep model of impending earthquake
Earthquake fractal zone creep of rocks relation of load short-term precursor
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2015/9/28
The alternative view of the current status and perspective of seismic prediction studies is discussed. In the problem of ascertainment of the uncertainty relation Cognoscibility-Unpredictability of Ea...
Post-seismic stress relaxation with a linear transient rheology
Transient rheology Geodynamics Stress tensor Coulomb failure function Post-seismic relaxation
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2015/8/28
We performed an analysis of post-seismic stress relaxation, taking into account generalized linear rheologies. We compared the stress field (and its derived functions) obtained with a classical Maxwel...