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Effective Charger Transfer Distances in Mixed-Valence Transition Metal Complexes
Charger Transfer Distances Mixed-Valence Transition Metal Complexes
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2016/5/23
Stark (electroabsorption) spectroscopy can provide quantitative information on the change in dipole moment and polarizability for an electronic transition. In the case of mixed-valence transitions, th...
Dipolar Character of Ligand-Centered Transitions in Transition Metal Tris-bipyridine Complexes
Stark spectra Tris-bipyridyl complexes UV spectroscopy Zn complexes
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2016/5/23
The Stark spectra of bipyridine (bpy) and the metaltris(2,2'-bipyridine) complexes of Zn, Fe, Ru and Os have been measured in the ligand-centered region in the near UV. The results show that excitatio...
R.F.-diode sputtered amorphous rare earth-transition metal films: microstructure, stability, and magneto-optical properties
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2011/12/1
We report the strong correlation of deposition parameters, microstructure and stability of r.f.diode sputtered magneto-optical thin films studied by transmission electron microscopy and a magneto-opti...
Universal phase transitions of B1 structured stoichiometric transition-metal carbides
Universal phase transitions
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2010/11/23
High-pressure phase transitions of B1 structured transition-metal carbides (TiC, ZrC, HfC, VC, NbC, TaC) were systematically researched by ab initio calculations. It was found that these carbides unde...
Efficient Algorithm for Asymptotics-Based CI and Electronic Structure of Transition Metal Atoms
Efficient Algorithm Asymptotics-Based CI Electronic Structure Transition Metal Atoms
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2010/10/19
Asymptotics-based CI methods1 are a class of Configuration-Interaction (CI) methods for atoms which reproduce,at fixed finite subspace dimension, the exact Schr¨odinger eigenstates in the limit of fix...
An efficient synthesis of Schiff bases containing benzimidazole moiety catalyzed by transition metal nitrates
Aldehyde 2-aminobenzimidazole catalyst Schiff bases
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2010/10/18
A simple and efficient method has been developed for the synthesis of some novel Schiff bases via the reaction of aromatic aldehydes with 2-aminobenzimidazole by using catalytic amount of M(NO3)2.xH2O...
Synthesis, characterization, and antibacterial effect of 4-methoxy-2-(5-H/Me/Cl/NO2-1H-benzimidazol-2-yl)- phenols and some transition metal complexes
4-Methoxy-benzimidazolylphenol, metal complexes, antibacterial activity
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2010/4/8
4-Methoxy-2-(5-H/methyl/chloro/nitro-1H-benzimidazol-2-yl)-phenol(HLX; X=1-4) ligands and HL1 complexes with Fe(NO3)3, Cu(NO3)2, AgNO3, and Zn(NO3)2 were synthesized and characterized. The structures...
The role of transition metal ions on HOx radicals in clouds: a numerical evaluation of its impact on multiphase chemistry
transition metal ions HOx radicals clouds multiphase chemistry
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2009/2/20
A new modelling study of the role of transition metal ions on cloud chemistry has been performed. Developments of the Model of Multiphase Cloud Chemistry (M2C2; Leriche et al., 2001) are described, in...
Biologically Active Transition Metal Chelates with a 2-Thiophenecarboxaldehyde-Derived Schiff Base: Synthesis, Characterization, and Antibacterial Properties
Schiff base transition metal complex biological activity
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2010/4/16
Metal complexes, ML2Cl2, where M is Fe(II), Co(II), Ni(II), Cu(II), Zn(II), or Cd(II), and L is the Schiff base formed by condensation of 2-thiophenecarboxaldehyde with 2-aminopyridine, N-(2-thienylme...
Synthesis, Thermal, Electrical and Catalytic Studies of Some Transition Metal Polychelates of Bis-bidentate Schiff Base
Schiff base polychelate TGA solid-state conductivity catalytic activity
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2007/12/20
Polychelates of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with the bis salen-type ligand derived from 4,4'-bis[(salicylaldehyde-5)azo]biphenyl and 1,4-diaminobutane have been synthesiz...
Comparison of Carboxylic and Hydroxycarboxylic Acids as Complexing Agents for Transition Metal Separation with Nonaqueous Capillary Electrophoresis
nonaqueous capillary electrophoresis transition metals carboxylic acids
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2007/12/13
Comparison of Carboxylic and Hydroxycarboxylic Acids as Complexing Agents for Transition Metal Separation with Nonaqueous Capillary Electrophoresis。
Ammonia Activation by Early Transition Metal Atoms (Sc, Ti, and V). Matrix Isolation Infrared Spectroscopic and Density Functional Theory Studies.
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2007/7/28
专著信息
书名
Ammonia Activation by Early Transition Metal Atoms (Sc, Ti, and V). Matrix Isolation Infrared Spectroscopic and Density Functional Theory Studies.
语种
英文
撰写或编译
作者
M. H. Chen,H. Lu,J. Dong,L. Mi...
过渡金属氧化物渗透对LSM-YSZ阴极性能的影响（Transition Metal Oxide Infiltration Effect on the Performance of LSM-YSZ Cathode）
SOFC LSM-YSZ阴极 过渡金属氧化物 渗透法
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2010/8/24
Transition metal (Mn, Fe, Co, Ni, Cu) oxide was formed in LSM-YSZ cathode by nitrate solution infiltration method. LSM-YSZ/YSZ/LSM-YSZ symmetric cell performance at intermediate temperature range 600～...
过渡金属掺杂Ru-Se簇合物电催化剂氧还原性能的对比研究（Comparison of Electrocatalytic O2 Reduction Performances between Transition Metal Doped Ru-Se Cluster）
氧电还原 Ru纳米簇硫族化合物 电催化剂 抗甲醇性
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2010/8/24
采用羰基金属化合物低温合成法制备了不同掺杂元素的M-Ru-Se(M=Fe，W，Mo)簇合物，并应用旋转圆盘电极电位扫描法测试簇合物的电催化活性及其抗甲醇性，采用TEM、XRD、EDS技术表征催化剂的微观形貌、结构和组成。结果显示，掺杂过渡元素对簇合物的催化活性及其抗甲醇性有明显的影响，其中Mo-Ru-Se的还原电流最高，催化活性最高，W-Ru-Se次之，Fe-Ru-Se最低；电解质中加入甲醇后，W...
Synthesis and Physico-chemical and Spectroscopic Investigations of Sodium Dihydrobis(1,2,3-benzotriazolyl)borate Ligand and Its Transition Metal Complexes
Dihydrobis(1,2,3-benzotriazolyl)borate ligand metal complexes spectral studies electronic spectra
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2010/4/19
The title ligand, sodium dihydrobis(1,2,3-benzotriazolyl)borate, Na[H2B(BTz)2], was synthesized by refluxing 1 mole of sodium borohydride with 2 moles of 1,2,3- benzotriazole in toluene. The ligand sh...