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Layered double hydroxide (LDH) compounds are characterized by structures in which layers with a brucite-like structure carry a net positive charge, usually due to the partial substitution of trivalent...
The extraction of alumina from bauxite by the Bayer process produces a slurry by-product referred to as ‘bauxite residue’ or ‘red mud’. The liquid component of the slurry is highly alkaline and requir...
Abstract: Adsorption and the mechanism of adsorption of the herbicide glyphosate [N-(phosphonomethyl) glycine] by hydrotalcite (HT) and by hydrotalcite calcined at 500°C (HT500) was studied. The value...
Abstract: Double hydroxide solids precipitated homogeneously from three laboratory-synthesized aqueous solutions that simulated mildly contaminated surface or groundwater. Over a limited pH range, pre...
The Cl NMR spectroscopy of Cl -intercalated hydrotalcite and the Ca-aluminate hydrate, the presence of hydrocalumite (Friedel°Os salt) demonstrates dynamical behavior of interlayer C dynamical orde...
Abstract: The thermal decomposition behavior of hydrotalcite-like compounds (HTlcs) prepared by reconstruction of calcined HTlcs is described. From the results of X-ray diffraction (XRD), it seems tha...
Historically, the decarbonation of Mg-Al-CO3 hydrotalcite-like compounds (HTlc) has been thought to occur between 400° and 500°C. The present work demonstrates that when HTlcs having the maximum Al co...
Alteration experiments have been performed using RTT7 and synthetic basaltic glasses in MgCl2-CaCl2 salt solution at 190∑C. The duration of experiments ranged from 0.25 to 463 days. The alteration pro...
Hydrotalcite (HT) interlayered with hexacyanoferrate(II) ions ([Mg4.62Al1.52(OH)12][(Fe(CN)6)0.30-(CO3)0.29]) has been synthesized from the carbonate-HT ([Mg4.52Al1.50(OH)12][(CO3)0.77]) through doubl...
Hydrotalcite-like compounds (HT) with 24%–48% Al3+-substitution have been synthesized in the Mg2+-Al3+-Fe(CN)64- system. Conditioning of the synthesized and air-dried compound with K4Fe(CN)64- solutio...
Polytype diversity of hydrotalcite-like minerals is mainly a function of the nature of the interlayer anion. Among the varieties with CO32− anions, only two- and three-layer polylypes having the...
All possible polytypes of hydrotalcite-like minerals with a periodicity along the c axis of one-, two- and three-layers, as well as the simplest six-layer polytypes, were derived on the basis of the c...
Infrared and Mössbauer spectroscopic studies were made on hydrotalcite-like materials, Mg6Al2(OH)16(NO3)2·4H2O, anion exchanged in aqueous solution of K3Fe(CN)6, K4Fe(CN)6·3H2O, or Na2Fe(CN)5NO·2...
Hydrotalcite-like compounds, described by the formula [Zn1-xAlx(OH)2][(CO3)x/2 · nH2O], were prepared by coprecipitation methods at 80°C and characterized by bulk chemical analysis, X-ray powder diffr...
Hydrotalcite-like minerals, containing Mg2+-Al3+-Xn- (Xn- = NO3-, Cl-, SO42-, or CrO42-), Zn2+-Al3+-NO3-, or Zn2+-Cr3+-NO3- ions, were intercalated with Co(CN)63- by an anion exchange method. For most...

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