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Abstract: The structure of Li- and Cs-montmorillonites was studied using infrared (IR) reflectance spectroscopy. The spectra of heat-treated clays between 80 and 220 °C were analyzed by Kramers-Kr&oum...
Na-montmorillonite (Na-MONT) was loaded with hexadecyltrimethylammonium cations (HDTMA) by replacing 41 and 90% of the exchangeable Na with HDTMA, labeled OC-41 and OC-90, respectively. Na-MONT, OC-41...
The desorption of benzoic acid and stearic acid from sodium and calcium montmorillonites has been studied using thermogravimetric and differential thermogravimetric analysis. Desorption of benzoic aci...
Abstract: Molecular dynamics computer simulations were used to study methanol molecules confined between the layers of 2:1 phyllosilicates. The model systems are based on natural Ca- and Na-rich montm...
Abstract: The adsorption and degradation of the herbicide triasulfuron [2-(2-chloroethoxy)-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzenesulfonamide] (CMMT) on homoionic Fe3+-, Al3+...
Abstract: Two series of pillared clays were prepared from a purified montmorillonite (95%) from La Serrata of Nijar, Spain, and polycations of Al and Zr using various methods. The effect of both the p...
Abstract: Montmorillonites saturated with Li+, Na+, K+, NH4+, Mg2+, Ca2+, Ba2+, or Ni2+ ions can form complexes with propylene carbonate (PC) by intercalation; the d(001) of montmorillonite expands to...
Abstract: Li+, Na+, Ca2+, Sr2+, Cu2+, or Zn2+-saturated samples of a cis-vacant montmorillonite from Linden, Bavaria, were heated to temperatures between 200–700°C. Half of each heated sample was subs...
Abstract: Monte Carlo simulations based on tested water-water, cation-water, and water-clay potential functions were applied to calculate radial distribution functions for O-O, O-H and H-H spatial cor...
Abstract: Cu-doped alumina-pillared montmorillonite samples have been prepared and characterized with X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), electron spin resonance (ESR) and inductive...
Abstract: Water inhibits sorption of uncharged organic compounds on montmorillonites saturated with small alkylammonium cations such as tetramethylammonium (TMA) and trimethylphenylammonium (TMPA). As...
Abstract: Montmorillonites saturated with small quaternary alkylammonium ions such as tetramethylammonium (TMA) or trimethylphenylammonium (TMPA) are excellent sorbents for aromatic pollutants. In som...
Abstract: Complexes formed between montmorillonite, saturated in Li+, Na+, Mg2+, Ca2+, Co2+, Fe3+, Cu2+ and Zn2+, and trimethyl phosphites (TMP) and triethyl phosphites (TEP) were studied. In all of t...
Methods previously used to distinguish between water adsorbed on external surfaces and in the interlamellar space of Na-montmorillonite during adsorption and desorption of water vapor have been extend...
Two samples, obtained by pillaring a Wyoming montmorillonite with hydroxy aluminium and oligosilsesquioxane cations, were studied by stepwise thermal desorption of ammonia and by highly sensitive diff...

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