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Cation ordering in lead-molybdenum-vanadium oxychlorides     Cation  lead-molybdenum-vanadium oxychlorides       font style='font-size:12px;'> 2012/4/9
The crystal chemistry and structure ofthe layered lead oxychloride parkinsonite, ideally Pb7Mo09C12, have been reevaluated in the light of TEM observations of natural and syn-thetic samples and the st...
The effects of compositional changes and nonsymmetry-breaking AI-Siordering onthe displacive phase transition in anorthoclase have been studied using X-ray powder diffrac-tion. The results wereanalyze...
Pressure induced ordering in (Ni,Mg)2SiO4 olivine     Pressure  (Ni,Mg)2SiO4  olivine       font style='font-size:12px;'> 2012/4/9
An imaging-plate detector interfaced to a large-volume high-pressure device allows quantitative in situ powder X-ray diffraction measurements at the National Synchrotron Light Source (NSLS). High-qual...
Mueller'smodelhasbeenwidelyapplied to modelingkineticexperimental data onthe ordering-disordering ofcations betweentwo nonequivalent sites.Thismodelis validonly for pure ornearly purebinary systems. F...
Curietemperatures (Td ofthe (Fe304)x(MgA1204)1-xsolid solution have been deter-minedfrom measurementsofmagneticsusceptibility (x)vs.temperature. Thetrend in Te vs.composition extrapolates to 0Katx =0...
The enthalpy ofordering ofAland Sibetween tetrahedral sites in framework structures is now known from several studies to bein the range 0.3-1.4 eVper two Al-O-Si linkages, depending on the structure a...
To explore the effect of pressure on the stacking-sequence of the chlorite cookeite, a systematic TEM study ofstacking microstructures has been conducted onnatural samples from pegmatitic and metamorp...
Kaolinite-richsamples wereselectedfor 27 Aland 29SiMASNMRstudy to explore the effectofFeontheir spectraandprovide insight into the nature ofFeorderingin kaolinite. Initial characterization bychemicala...
In studies on the fate of aluminium in the environment, nontronite and saponite have been obtained by synthesis in reducing alkaline conditions close to those prevailing in poorly drained soils develo...
The 57Fe M鰏sbauer spectra of six nontronite samples were measured at appropriate temperatures of 4.2 and 1.3 K. Three of the nontronites gave a complex magnetic hyperfine spectrum showing magnetic ord...
Review of Cation Ordering in Micas     Cation ordering  Lepidolite  Margarite  Mica  Muscovite  Paragonite  Phengite       font style='font-size:12px;'> 2012/2/2
Long-range ordering of tetrahedral cations in micas is favored by phengitic compositions, by the 3T stacking sequence of layers, and by tetrahedral Si:Al ratios near 1:1. Phengites of the 1M, 2M1, and...
To explain the large values of the quadrupole splittings and line widths in the M鰏sbauer spectrum of oxybiotite, a formalized analysis of the distribution of effective charges in the anion network was...
Cation Ordering Pattern in Amesite     Amesite  Antarctica  Cation Ordering  Twinning       font style='font-size:12px;'> 2012/2/10
Cation ordering in amesite-2H2 from Antarctica has reduced the true symmetry from the ideal hexagonal space group P63 to triclinic P1. All crystals show 6-fold biaxial twin sectors on (001), and the t...
The Ordering of Cetylpyridinium Bromide on Vermiculite     Adsorption  Cetylpyridinium  Exchange  Interlayer  Superlattice  Vermiculite       font style='font-size:12px;'> 2012/2/10
X-ray superlattice reflections, infrared spectroscopy, and chemical analyses have established that cetylpyridinium bromide (CPB) is highly ordered when adsorbed on vermiculite. The molecules, which st...

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