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6种芳香植物精油的提取及综合品质评价     精油  出油率  灰色关联度  综合评价       font style='font-size:12px;'> 2009/11/10
[目的] 为芳香精油的生产提供理论指导。[方法] 分别从蓝桉、猴樟、香叶天竺葵、柠檬草、薄荷和柑橘中提取芳香精油,然后比较其出油率并采用灰色关联度法对6种精油的品质进行综合评价。[结果] 蓝桉、猴樟、香叶天竺葵、柠檬草、薄荷和柑橘的平均出油率分别为0.86%、0.33%、0.24%、1.29%、1.27%和1.88%。精油颜色由亮到暗为:猴樟>薄荷>蓝桉>柠檬草>香叶天竺葵>柑橘;香味强弱为:柠檬...
氟虫腈所含主要微量杂质的相关研究     氟虫腈  杂质  结构鉴定       font style='font-size:12px;'> 2009/9/16
[目的] 分析氟虫腈产品所含的主要微量杂质。[方法] 利用MS、NMR、IR等光谱分析技术对用拜尔公司工艺生产的氟虫腈产品所含的主要微量杂质进行初步分析和结构鉴定。 [结果] 氟虫腈成品中所含的主要杂质是(±)5氨基1(2,6二氯α,α,α三氟p甲苯基)4三氟甲基磺酰基3氰基吡唑。追溯杂质的来源,发现该杂质和氟虫腈最后一步生产工艺的氧化反应有关。不加催化剂,仅用双氧水则...
经过近6年的不懈努力,中国科学院上海有机化学研究所刘文课题组的专家通过最为典型的硫链丝菌素及其类似物盐屋霉素A的比较研究,发现硫肽类抗生素起源于一条核糖体编码的前体肽,经过包括环化脱水/脱氢形成噻唑/咪唑环、脱水形成脱水氨基酸以及【4 + 2】环合反应等后修饰步骤构建了这一家族化合物所共有的特征性结构(Liao, R. et al. Chem. & Biol. 2009, 16, 141)。
The transesterification of canola oil to fatty acid methyl esters was studied using Amberlyst-26 as a solid catalyst. The influence of reaction conditions, such as the reaction time, methanol to oil m...
Thin-layer chromatography on rice starch support and aqueous ammonia--organic modifier (methanol, dioxane, and acetone) mobile phases was used to study the effect on retention of the chromatographic s...
A series of 8 new derivatives of fendiline was prepared for evaluation as allosteric modulators of GABAB receptors: 4 based on acridine and 4 with restricted distance between the 2 aryl moieties.
1,4'-Diazaflavone pigment (2) was synthesized by a simple environmentally friendly microwave-assisted one-pot method for the cyclization of 2'-amino (E)-4''-aza-chalcone (1) under solventless conditio...
This paper examines the synthesis of g-butyrolactone compounds 2, 3, 4, 5, and 9, and their potential antimicrobial nature and ability. The structures of all the compounds mentioned above were determi...
Some 3(2H)-pyridazinone and 1(2H)-phthalazinone derivatives were synthesized. The structures of these new compounds were confirmed by IR, 1H-NMR, mass spectrum, and elemental analysis. The synthesized...
4(5)-Chloro-imidazole-5(4)-carboxaldehyde derivatives are important precursors for the preparation of biologically active compounds. We developed a simple, novel, and efficient method for the synthesi...
Salicylaldehyde and some of its derivatives react with urea (or thiourea) and ethyl acetoacetate (the Biginelli reaction) to give products that depend on the type of the substituent in the ortho-posit...
探讨了APE1547蛋白的β-推进器结构中第3和第4“叶片”间的侧链氢键(Thr127-Gly154, Leu182-Arg145-Glu122)对蛋白质的作用.
A natural cyclic octapeptide cherimolacyclopeptide G (8) was synthesized by coupling of tetrapeptide units Boc-Gly-Ala-Val-Pro-OMe (5) and Boc-Ile-Tyr-Ala-Pro-OMe (6) after proper deprotection at carb...
3-[(5-Amino-1,3,4-thiadiazol-2-yl)methyl]-4-ethoxycarbonylamino-5-alkyl-4H-1,2,4-triazoles (2a,b) were obtained from the reaction of 3-cyanomethyl-5-alkyl-4-ethoxycarbonylamino-4H-1,2,4-triazoles (1a...
王谨晔(JY Wang)          font style='font-size:12px;'> 2007/12/29
王瑾晔 博士 女,1965年1月出生,现为中国科学院上海有机化学研究所研究员,课题组长。 Tel: 021-54925330 Fax: 021-64166128 E-mail: jywang@mail.sioc.ac.cn 主要学习与工作经历 1. 1981.9-1985.7 河南师范大学化学系毕业,理学博士 2. 1987.4-1992.3 日本东北大学农学研究科,农学博士 3....

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