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Layered double hydroxide (LDH) compounds are characterized by structures in which layers with a brucite-like structure carry a net positive charge, usually due to the partial substitution of trivalent...
The extraction of alumina from bauxite by the Bayer process produces a slurry by-product referred to as ‘bauxite residue’ or ‘red mud’. The liquid component of the slurry is highly alkaline and requir...
Hetero-polyacid anions (PW12O403-)-pillared hydrotalcite-like compound is directly and hydrothermally synthesized by the hot solution method. FTIR and XRD show that PW12O403- has been incorporated int...
Biodiesel produced by the transesterification of vegetable oils is a promising alternative fuel to diesel because of limited fossil fuel resources and environmental concerns. The use of heterogeneous ...
期刊信息 篇名 Stoichiometric synthesis of a pure ferrite from a tailored layer double hydroxide (hydrotalcite-like) precursor 语种 英文 撰写或编译 撰写 作者 Junjie Liu,Feng Li,David G. Evans,Xue Duan 第一作者单位 刊物名称 Chem. C...
采用晶体学理论建立二元类水滑石(LDHs)微观结构模型与静电势能模型,将层板金属离子间距、层板电荷密度、层间阴离子间距等微观结构参数定量化,并将层间阴离子的静电势能表示成层板金属离子半径和物质的量之比、插层阴离子尺寸和电荷的函数。研究结果表明:LDHs层板金属离子间距应用离子紧密堆积来估算和孔径按阴离子平面六方点阵分布来计算是可行的;调变层板金属离子种类与物质的量之比影响层间阴离子的稳定性,势能计...
Abstract: Adsorption and the mechanism of adsorption of the herbicide glyphosate [N-(phosphonomethyl) glycine] by hydrotalcite (HT) and by hydrotalcite calcined at 500°C (HT500) was studied. The value...
Abstract: Double hydroxide solids precipitated homogeneously from three laboratory-synthesized aqueous solutions that simulated mildly contaminated surface or groundwater. Over a limited pH range, pre...
The Cl NMR spectroscopy of Cl -intercalated hydrotalcite and the Ca-aluminate hydrate, the presence of hydrocalumite (Friedel°Os salt) demonstrates dynamical behavior of interlayer C dynamical orde...
Abstract: The thermal decomposition behavior of hydrotalcite-like compounds (HTlcs) prepared by reconstruction of calcined HTlcs is described. From the results of X-ray diffraction (XRD), it seems tha...
Historically, the decarbonation of Mg-Al-CO3 hydrotalcite-like compounds (HTlc) has been thought to occur between 400° and 500°C. The present work demonstrates that when HTlcs having the maximum Al co...
Alteration experiments have been performed using RTT7 and synthetic basaltic glasses in MgCl2-CaCl2 salt solution at 190∑C. The duration of experiments ranged from 0.25 to 463 days. The alteration pro...
Hydrotalcite (HT) interlayered with hexacyanoferrate(II) ions ([Mg4.62Al1.52(OH)12][(Fe(CN)6)0.30-(CO3)0.29]) has been synthesized from the carbonate-HT ([Mg4.52Al1.50(OH)12][(CO3)0.77]) through doubl...
Hydrotalcite-like compounds (HT) with 24%–48% Al3+-substitution have been synthesized in the Mg2+-Al3+-Fe(CN)64- system. Conditioning of the synthesized and air-dried compound with K4Fe(CN)64- solutio...
Polytype diversity of hydrotalcite-like minerals is mainly a function of the nature of the interlayer anion. Among the varieties with CO32− anions, only two- and three-layer polylypes having the...

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