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Manganese(III) Acetate Mediated Free Radical Cyclization of 1,3-Dicarbonyl Compounds with Sterically Hindered Olefins
Manganese(III) acetate free radical cyclization 1,3-dicarbonyl 4,5-dihydrofuran tetrahydrobenzofuran trifluoroacetyl oxidative addition
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2010/4/19
The manganese(III) acetate mediated radical cyclization of dimedone 1a, 2,4-pentanedione 1b, ethyl acetoacetate 1c, 1,3-cyclohexanedione 1d and 5-phenyl-1,3-cyclohexanedione 1e with 1,1-diphenyl-1-but...
Reactions of N-Aminopyrimidine Derivatives with 1,3-Dicarbonyl Compounds
Enamine Imine 1,3-Diketone Addition reaction
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2010/6/29
The reactions of 1-Amino-pyrimidine derivatives (1) and some 1,3-dicarbonyl compounds (2) were realized in the presence of p-toluensulfonic acid catalyst to give convenient enamine (3) and/or imine de...