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Weathering products formed on the surface of K-feldspar in Yakushima Island, Japan were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron micros...
Terminal phenolic hydroxyl triazine dendrimer (HTHP) was prepared by putting cyanuryl chloride and 1,3,5-benzenetriol into acetone and then adding K2CO3 into the mixture as deacid reagent, which is ca...
Abstract: OH-Al solutions were prepared by adding appropriate amounts of NaOH to AlCl3 to obtain OH/Al mole ratios of 2.0, 2.5, 2.7, 3.0, and 3.3 in the final suspension. Solid Na2SO4 and Georgia kaol...
Abstract: Oxygen-isotope data were obtained for synthetic aluminum-hydroxide phases precipitated over 65–125 mo and have been compared to results from similar experiments conducted for 3–56 mo. The Al...
Five-Coordinate Aluminum in Allophane     Allophane  Five-coordinate Aluminum  NMR Spectroscopy   Silica Springs       font style='font-size:12px;'> 2011/12/2
Abstract: Samples of Silica Springs allophane from Tongariro National Park, New Zealand, having Al/Si atomic ratios in the range 1.1–1.9, were studied by 27Al nuclear magnetic resonance (NMR) spectros...
Abstract: Double hydroxide solids precipitated homogeneously from three laboratory-synthesized aqueous solutions that simulated mildly contaminated surface or groundwater. Over a limited pH range, pre...
Ab initio, molecular orbital calculations for two different Hartree-Fock basis levels were performed on clusters in the system Al-O-H, and tested by comparing derived vibrational frequencies to the me...
An atomistic computer simulation study was undertaken to address the role of Al in the substitution of ferric iron into magnesium silicate perovskite, MgSiO 3. Calculated substi-tution and vacancy en...
Abstract: The Crystal Packer module in the Cerius2 modeling environment has been used to study the structure of montmorillonite intercalated with Al(OH)3-fragment (gibbsite-like) polymers. Basal spaci...
Abstract: The structure of montmorillonite intercalated with [Al13O4(OH)24+x(H2O)12−x](7−x)+ cations ( A l 13 (7−x)+ for short), where x = 0, 2 and 4, has been studied using the Ceri...
Abstract: The hydrothermal synthesis of Mg-beidellite in which limited amounts of Ga and Cr are clearly shown to be incorporated into nonexchangeable positions in the clay layer framework is reported ...
Abstract: Surface adsorption mechanisms of dissolved inorganic carbon species on soil minerals are not well understood. Traditional infrared (IR) study of adsorbed species of inorganic carbon using ai...
Abstract: The uptake of Sr and Cs by 2 types of aluminum pillared layered clays (Al-PILC), a reference sample (AZA) and a specially tailored sample (FRAZA), were investigated. The AZA sample was prepa...
Abstract: We studied the influence of time ageing (up to 120 d at 50°C or 30d at 95°C) on the mineralogical and chemical composition of hydrolytic species of mixed aluminum and iron samples formed at ...
Abstract: The influence of different ions in the formation of Al(OH)3 polymorphs has been studied experimentally by promoting stoichiometric reactions between the aluminum salts (AlCl3, Al(NO3)3, Al2(...

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