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Energetics of Primary Charge Separation in Bacterial Photosynthetic Reaction Center Mutants:Triplet Decay in Large Magnetic Fields
horseradish peroxidase lignin peroxidase enzymatic oxidations N-demethylation methylene blue azure B azure C
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2016/5/24
The triplet state of aromatic molecules forms and decays by intersystem crossing, as originally demonstrated by Kasha and Lewis. By contrast, the triplet state of the primary electron donor, 3 P, in p...
The Effect of Very High Magnetic Fields on the Reaction Dynamics in Bacterial Reaction Centers:Implications for the Reaction Mechanism
Reactioncenter Photosynthesis Bacterialphotosynthesis Delayedfluorescence Magnetic fieldeffect (Rb. sphaeroides)
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2016/5/23
Magnetic field effects have proven to be a powerful tool for elucidating the mechanism of the initial charge separation and recombination steps in bacterial photosynthesis. Since the first data were o...
The Effect of Very High Magnetic Fields on the Delayed Fluorescence from Photosynthetic Reaction Centers
Reactioncenter Photosynthesis Bacterialphotosynthesis Delayedfluorescence Magneticfieldeffect (Rb. sphaeroides)
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2016/5/23
Delayed fluorescence is observed from quinone-depleted Rhodobacter sphaeroides reaction centers due to re-formation of the excited state of the special pair electron donor from the initially formed ra...
Energetics of Initial Charge Separation in Bacterial Photosynthesis:The Triplet Decay Rate in Very High Magnetic Fields
Photosynthesis Electron transfer Reaction center Magnetic field effect primary electron acceptor primary electron donor quinone
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2016/5/20
The triplet state of the primary electron donor is formed in bacterial reaction centers when electron transfer to the quinone is blocked. The relative quantum yield of formation and the rate of decay ...